CLEAN INSTALL OF WINDOWS XP.

The Preparation
A clean install in Windows XP is a very easy process. Just as there are certain things that need to be done to complete a successful upgrade, the same is needed with a clean install. First, check the requirements for Windows XP.  Check the requirements for the appropriate version below.

Windows XP Home Edition System Requirements
Windows XP Professional Edition System Requirements

The next step is to check the Windows XP Hardware Compatibility List Here to see if it's supported. It's possible, even likely, that one or more of your items won't be on the last. That doesn't mean you have to replace them or that they won't work with XP, but it does mean you should visit the manufacturers site to check for XP drivers. In some cases the Windows 2000 drivers will work just fine. The point is, make sure you have the drivers downloaded and saved where they will be available during the XP installation. Drivers for RAID and SCSI devices fall into this same category. Make sure they are available at the beginning of the installation process.
Microsoft has made available on their website some excellent documentation regarding upgrading to Windows XP. I strongly suggest it be read before a final decision is made. A number of other articles are linked from the one below, including a download location for the Microsoft Windows Upgrade Advisor. Even though it's a 35MB download, running it will alert you to any hardware and software problems that may be encountered in your XP installation.
Description of the Windows XP Upgrade Advisor Here
If you aren't familiar with the differences between FAT32 and NTFS file systems, now is the time to rectify that situation. This will be the most important decision you have to make during the installation process so a bit of knowledge can be very valuable. See the article linked below.
Description of the FAT32 File System in Windows XP Here.
In my opinion use NTFS for security reasons, and with NTFS you can also use bigger HDD's.
The Installation
There are two methods  for installing Windows XP, both requiring the first step of booting your machine. You're in luck if the box is capable of booting from the CD-ROM drive since the Windows XP CD's are bootable. If no you'll need a set of Setup Startup Disks you can find those Here. Most computers that will be happy running XP have the capability to boot from the CD. It's probably a red flag if you need the startup disks, so take one more look at the minimum and recommended requirements for running Windows XP. If it's still a go, download the file that will create the disk sets for either the Home Edition or the Professional Edition. Make the disk set, boot the computer and insert the XP CD to begin the installation.
For Machines that support booting from the CD, the following steps will get you through the clean install of Windows XP.
Turn on the computer and insert the XP CD.
Watch the monitor for the message that the CD has been auto-detected, followed by the Press any key to boot CD message. Just hit the spacebar or any other key that's convenient within the five second time span the message will be displayed.
Files will start to load from the CD to begin the installation. Eventually you'll be asked if you want to install Windows XP. No need to type an essay here on why you've made the decision to do the installation. Just hit Enter.
Next is the End User License Agreement or EULA which must be accepted to continue installation. Press F8 to accept, F3 to bail out now. You can read the EULA if you want, but it adds two days to the installation time.
The next screen displays the available partitions where XP can be installed. Select the one you want and tap that Enter key again to move on to the screen where you select a file system.
It's time for that important decision. FAT32 versus NTFS. The preferred choice is NTFS. It allows security features and stability that aren't possible with FAT32. Apply the knowledge you gained during the preparation phase at this point. Make your choice of formatting options and press the F key to start the process. Once the format process completes the installation will continue.
If you are installing from a full version Windows XP CD the installation continues without intervention. If you're using an upgrade version CD this is where Microsoft confirms your eligibility by requesting the media that allows you to use the upgrade version. Insert your media in the drive, let the verification complete and reinsert the XP CD when prompted.
Setup continues and eventually the computer will reboot. Watch the onscreen prompts but do not press a key when the Press any key to boot CD message appears.
Installation will continue, prompting you from time to time to supply some additional setup information. Feed the prompts with appropriate responses and eventually another reboot will occur, this time bringing you back into Windows XP, depositing you at the Windows Activation screen.
You can either activate your copy of XP now or delay the activation for up to 30 days and suffer the periodic activation reminders. I suggest you activate now and register at the same time. It's really painless. In any case, activation is required at some point or after 30 days you'll be denied access to the desktop. Registration is entirely optional.
The last step is to enter a username and watch the XP desktop appear, ready for use.

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